Formation mechanism of a crystalline Ag50Pd50 solid solution by impact ball–materials interaction

Abstract

The formation of the crystalline Ag₅₀Pd₅₀ solid solution during mechanical alloying under shock interaction of Ag and Pd metallic powders has been studied using electron microscopy and X-ray diffraction. The process involved for impact interaction occurs via the incorporation of the small Pd particles into the Ag matrix in which, under the action of mechanical strain, the mutual diffusion of Ag and Pd leads to the formation of two solid solutions, one rich in Ag and the other rich in Pd. Further grinding allows the homogenization of the two Ag and Pd solid solutions whose composition changes to finally reach the initial Ag₅₀Pd₅₀ composition. The defects as dislocations generated by the impact conditions may be responsible for the reaction mechanism.