TlSr2NiO4 +δ has been synthesised by reaction of Tl2O3 and Sr2Ni2O5 in a sealed gold tube at 950 °C. The compound is isostructural with the orthorhombic form of TlSr2CuO4 +δ with alternating TlO and oxygen-deficient (NiO)2 –x layers.
C. S. Knee and M. T. Weller, J. Mater. Chem., 1996, 6, 1449 DOI: 10.1039/JM9960601449
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