The synthesis and characterization of new bridged phthalocyaninatoruthenium complexes of the types PcRuL2 and [PcRu(L)]n using 1,2,4-triazines as bridging ligand are reported. The preferred coordination of N1 of the 1,2,4-triazines with the metal atom in PcRuL2 is discussed based on NMR spectroscopy. The oligomers 14–20 prepared exhibit good semiconducting properties without external doping.
J. Pohmer, M. Hanack and J. O. Barcina, J. Mater. Chem., 1996, 6, 957 DOI: 10.1039/JM9960600957
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