X-Ray structural analyses of the charge-transfer complex (EDT–TTFC12)2·TCNQF4, 2, and the radical cation salt EDT–TTFC12·ClO4, 3, revealed an interesting effect of chlorine substitution on the crystal stacking mode; the electrical conductivity of 2 is unusually high, although it has a mixed-stacking structure.
M. Iyoda, H. Suzuki, S. Sasaki, H. Yoshino, K. Kikuchi, K. Saito, I. Ikemoto, H. Matsuyama and T. Mori, J. Mater. Chem., 1996, 6, 501 DOI: 10.1039/JM9960600501
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