Densities have been measured of aqueous solutions of ethylene glycol oligomers at 25 °C. Expressions for the limiting partial molar volumes were obtained: V2=V02+V22X2. Both V02 and V22 were found to be linear functions of the ethoxy group (—CH2—O—CH2—) number. The Kirkwood–Buff theory was used to interpret the V2 behaviour.
L. Ambrosone, R. Sartorio, A. Vescio and V. Vitagliano, J. Chem. Soc., Faraday Trans., 1996, 92, 1163 DOI: 10.1039/FT9969201163
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