The reaction between BiCl3 and 3 equivalents of Li[NHR](R = 2,6-Me2C6H3) afforded the trinuclear bismuth imidoamide species [Bi3(µ-NR)4(NHR)] whilst BiPh3 and 3 equivalents of the alcohol HOR′(R′= 2,6-Cl2C6H3) gave the hexanuclear oxoalkoxide compound [Bi6(µ3O)3(µ-OR)7(OR)5] both of which have been characterised by X-ray crystallography.
S. C. James, N. C. Norman, A. G. Orpen, M. J. Quayle and U. Weckenmann, J. Chem. Soc., Dalton Trans., 1996, 4159 DOI: 10.1039/DT9960004159
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...