Issue 22, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Build-up of an Al4P6Li4 cage from an Al4N4 cubane: synthesis and structure of [Li(OC4H8)]4[{(AlMe)[µ-P(C6H11)]}2{µ-P(C6H11)}]2·C6H5Me

Robert E. Allan,   Michael A. Beswick,   Paul R. Raithby,   Alexander Steiner  and  Dominic S. Wright  

Abstract

The acid–base reaction of the AlIII imido cubane [AlMe(Nmes)]4(mes = 2,4,6-Me3C6H2) with Li[PH(C6H11)] yielded the heterobimetallic cage complex [Li(OC4H8)]4[{(AlMe)[µ-P(C6H11)]}2{µ-P(C6H11)}]2·C6H5Me, the metallacyclic tetraanion of which is the first example of an AlIII phosphinidine anion.

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Article information

DOI
https://doi.org/10.1039/DT9960004153
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 4153-4154

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Build-up of an Al4P6Li4 cage from an Al4N4 cubane: synthesis and structure of [Li(OC4H8)]4[{(AlMe)[µ-P(C6H11)]}2{µ-P(C6H11)}]2·C6H5Me

R. E. Allan, M. A. Beswick, P. R. Raithby, A. Steiner and D. S. Wright, J. Chem. Soc., Dalton Trans., 1996, 4153 DOI: 10.1039/DT9960004153

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