A novel aluminium methylphosphonate, with unit cell composition [Al(OH)PO3Me·H2O]4, has been prepared hydrothermally; the structure consists of parallel chains of aluminium–oxygen octahedra linked via bridging oxygens and methylphosphonate groups to give inorganic sheets partially covered on both surfaces by methyl groups.
L. Sawers, V. J. Carter, A. R. Armstrong, P. G. Bruce, P. A. Wright and B. E. Gore, J. Chem. Soc., Dalton Trans., 1996, 3159 DOI: 10.1039/DT9960003159
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