Issue 14, 1996

Codimerisation of CO and a 1,3-diynyl–metal complex on an Ru3 cluster

Abstract

The reaction of [W(C[triple bond, length half m-dash]CC[triple bond, length half m-dash]CH)(CO)3(cp)] with [Ru33HC2C[triple bond, length half m-dash]C[W(CO)3(cp)]}(µ-CO)(CO)9(cp =η-C5H5) afforded an unusual WRu3 cluster bearing a ligand formed by dimerisation of the diynyl ligand with incorporation of two molecules of CO, as shown by a crystal-structure determination.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 3151-3152

Codimerisation of CO and a 1,3-diynyl–metal complex on an Ru3 cluster

M. I. Bruce, B. W. Skelton, A. H. White and N. N. Zaitseva, J. Chem. Soc., Dalton Trans., 1996, 3151 DOI: 10.1039/DT9960003151

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