Issue 13, 1996

Photophysics and photochemical reactivities of organocopper(I) complexes. Crystal structure of [Cu2(PPh2Me)4(µ,η1-C[triple bond, length half m-dash]CPh)2]

Abstract

Dimeric [Cu2(PPh2Me)4(µ,η1-C[triple bond, length half m-dash]CPh)2] has been synthesized and crystallographically characterized; its photophysics together with those of other related organocopper(I) complexes, [Cu2{2-C(SiMe3)2C5H4N}2] and [{Cu(C6H2Me3-2,4,6)}5] have been studied and Stern–Volmer quenching data of the phosphorescent state of the pyridine complex with organic halides are suggestive of a charge-transfer mechanism with a high driving-force regime.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 2889-2891

Photophysics and photochemical reactivities of organocopper(I) complexes. Crystal structure of [Cu2(PPh2Me)4(µ,η1-C[triple bond, length half m-dash]CPh)2]

V. W. Yam, W. Lee, K. K. Cheung, H. Lee and W. Leung, J. Chem. Soc., Dalton Trans., 1996, 2889 DOI: 10.1039/DT9960002889

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