The dinuclear manganese(IV) complex [Mn2O3L2][PF6]2 exhibits high activity for 8-hydroxy-2′-deoxyguanosine formation and relaxation of pBR322 form I DNA in the presence of H2O2, where L = 1,4,7-trimethyl-1,4,7-triazacyclononane; the active species is postulated to be a unidentate peroxide adduct of the manganese(IV) complex.
T. Kobayashi, K. Tsuchiya and Y. Nishida, J. Chem. Soc., Dalton Trans., 1996, 2391 DOI: 10.1039/DT9960002391
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