Metal complexes of a tetrathiafulvalene 4,5-dithiolate. Synthesis, characterisation and properties of dianionic and neutral mercury complexes

Abstract

Dianionic mercury bis(tetrathiafulvalene dithiolate) complexes [NMe₄]₂[Hg(R₂C₆S₈)₂](R = Et or Bu) and the corresponding oxidised neutral complex [Hg(R₂C₆S₈)₂](R = Et) have been prepared. The crystal structure of [NMe₄]₂[Hg(R₂C₆S₈)₂](R = Et) has been determined and shows that the tetrathiafulvalene dithiolate units are tetrahedrally co-ordinated around the central Hg atom. Cyclic voltammetry and ESR studies indicated that there is very little interaction between the two ligands. A compressed pellet of the powdered neutral complex exhibited an electrical conductivity of 10^–5 S cm^–1 at room temperature.