The new pendant-arm macrocycle (5S, 7S, 12R, 14R)-tetramethyl-6,13-dinitro-1,4,8,11-tetraazacyclotetradecane (L1) has been synthesised as its copper(II) complex and its crystal structure revealed a rare example of genuine square-planar co-ordination; reduction of [CuL1]2+ affords the metal-free diamino-substituted analogue.
P. V. Bernhardt, K. A. Byriel, C. H. L. Kennard and P. C. Sharpe, J. Chem. Soc., Dalton Trans., 1996, 145 DOI: 10.1039/DT9960000145
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