Issue 1, 1996
From the journal:

Journal of the Chemical Society, Dalton Transactions

Redox considerations for a ruthenium complex catalysis of substrate oxidation by hydrogen peroxide in aqueous solution

Michael H. Robbins  and  Russell S. Drago  

Abstract

The pH dependence of the redox chemistry of [Ru(dmphen)2(H2O)]2+ has been measured (dmphen = 2,9-dimethyl-1, 10-phenanthroline). Comparison of the results with those for similar complexes illustrates the unique acidity of the co-ordinated waters and the large oxidizing strength of the ruthenium. The reaction of [Ru(dmphen)2(H2O)2]2+ with H2O2 has been studied as a function of pH and the results are used to provide a mechanism for the catalysis of alkane oxidation by this complex.

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Article information

DOI
https://doi.org/10.1039/DT9960000105
Article type
Paper

J. Chem. Soc., Dalton Trans., 1996, 105-110

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Redox considerations for a ruthenium complex catalysis of substrate oxidation by hydrogen peroxide in aqueous solution

M. H. Robbins and R. S. Drago, J. Chem. Soc., Dalton Trans., 1996, 105 DOI: 10.1039/DT9960000105

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