Only (E)-fluoroalkenic products are obtained when racemic 9- and 10-fluoro fatty acids are processed by a Saccharomyces cerevisiaeΔ9 desaturase as determined by 1H- decoupled 19F NMR and GC–MS analysis; no evidence for hydroxylated intermediates was found.
P. H. Buist, B. Behrouzian, K. A. Alexopoulos, B. Dawson and B. Black, Chem. Commun., 1996, 2671 DOI: 10.1039/CC9960002671
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