The phosphorus-bridged [1]ferrocenophane Fe(η-C5H4)2-PPh undergoes living anionic ring-opening polymerization at 25 °C in THF using BunLi as initiator to yield monodisperse poly(ferrocenylphosphines) of controlled molecular mass and novel block copolymers with potentially coordinating phosphorus atoms in one segment.
C. H. Honeyman, T. J. Peckham, J. A. Massey and I. Manners, Chem. Commun., 1996, 2589 DOI: 10.1039/CC9960002589
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