X-Ray structural studies of the two redox-related pairs [Cr(CO)2(η-PhC![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CPh)(η6-C6HMe5)]0/1+ and [Mo(CO)2(η-PhCPh)(Tp′)]0/1+[Tp′= hydrotris(3,5-dimethyl-pyrazolyl)borate] are consistent with the HOMO of the d6, Cr0 alkyne complex being an antibonding M–alkyne π⊥ orbital.
I. M. Bartlett, N. G. Connelly, A. G. Orpen, M. J. Quayle and J. C. Rankin, Chem. Commun., 1996, 2583 DOI: 10.1039/CC9960002583
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