Issue 22, 1996

First dicopper(II) complex to contain bridging macrocyclic pyridazine units: structure, electrochemistry and magnetochemistry of [Cu2L(MeCN)2(ClO4)2][ClO4]2

Abstract

Magnetic and electrochemical studies of the structurally characterised dicopper(II) complex [Cu2L(MeCN)2-(ClO4)2][ClO4]2 1, the first to be bridged by two pyridazine units held within a (2 + 2) macrocyclic ligand, reveal strong antiferromagnetic exchange as well as two well separated reversible one-electron reductions at positive potentials.

Article information

Article type
Paper

Chem. Commun., 1996, 2579-2580

First dicopper(II) complex to contain bridging macrocyclic pyridazine units: structure, electrochemistry and magnetochemistry of [Cu2L(MeCN)2(ClO4)2][ClO4]2

S. Brooker, R. J. Kelly, B. Moubaraki and K. S. Murray, Chem. Commun., 1996, 2579 DOI: 10.1039/CC9960002579

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