Issue 21, 1996

First α,β-unsaturated mononuclear bisylidene complex of tungsten: synthesis and structure

Abstract

cis-Tetracarbonyl[(1-cyclopentenyl)(N-morpholino)methylidene](2-hydroxyphenyl isocyano)tungsten(0) 5 undergoes intramolecular cyclization by deprotonation and subsequent N-alkylation to give the novel bisylidene complex 6, which is characterized by a single-crystal X-ray structure analysis.

Article information

Article type
Paper

Chem. Commun., 1996, 2455-2456

First α,β-unsaturated mononuclear bisylidene complex of tungsten: synthesis and structure

J. Barluenga, F. Aznar, B. Weyershausen, S. Garcí-Granda and E. Martín, Chem. Commun., 1996, 2455 DOI: 10.1039/CC9960002455

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