Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene and -allylbenzene; evidence for novel carbon–carbon double and triple bond cleavage and alkyne insertion reactions
Abstract
Reaction of [W(η2-PhC2Ph)3(NCMe)] with o-diphenylphosphino-styrene or -allylbenzene leads to either novel reorganisation reactions involving cleavage of carbon–carbon double and triple bonds, or unusual insertion reactions by PhC2Ph into carbon–hydrogen bonds.
Please wait while we load your content...