Crystalline anhydrous bis(acetato)manganese(II) is isolated from superheated acetonitrile under autogeneous pressure; the single-crystal X-ray structure reveals a covalently linked three-dimensional network with six- and seven-coordinate manganese (II) centres.
J. D. Martin and R. F. Hess, Chem. Commun., 1996, 2419 DOI: 10.1039/CC9960002419
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