Oxochromimum(V) centers initiate DNA cleavage through a chromium(V)-phosphate diester intermediate by hydrogen abstraction from the C1′ position of the ribose sugar, leading to the formation of 5-methylene-2-furanone, 3′-phosphate terminus and DNA bases; by contrast a plasmid DNA (pUC19)is only nicked.
R. N. Bose and B. S. Fonkeng, Chem. Commun., 1996, 2211 DOI: 10.1039/CC9960002211
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