Issue 16, 1996

Role of chlorocarbon oligomers in the room-temperature heterogeneous catalytic fluorination of hydrochlorocarbons to hydrochlorofluorocarbons

Abstract

Radiotracer [18F] and [36Cl] experiments demonstrate the deposition of oligomeric chlorocarbon species on fluorinated metal oxides and trapping of hydrochlorocarbon monomers, both without loss of surface fluoride lability, thus accounting for the unusual room-temperature heterogeneous catalytic fluorination of CH3CCl3 and related species by anhydrous HF.

Article information

Article type
Paper

Chem. Commun., 1996, 1947-1948

Role of chlorocarbon oligomers in the room-temperature heterogeneous catalytic fluorination of hydrochlorocarbons to hydrochlorofluorocarbons

A. Bendada, D. W. Bonniface, F. McMonagle, R. Marshall, C. Shortman, R. R. Spence, J. Thomson, G. Webb, J. M. Winfield and N. Winterton, Chem. Commun., 1996, 1947 DOI: 10.1039/CC9960001947

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