Starting from organic fragments, a [2]-rotaxane is constructed using pure coordination chemistry; threading of a string into a ring is directed by CuI complexation and the blocking reaction involves coordination of RuII to terminal chelates.
D. J. Cárdenas, P. Gaviña and J. Sauvage, Chem. Commun., 1996, 1915 DOI: 10.1039/CC9960001915
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