Issue 16, 1996
From the journal:

Chemical Communications

Complete metal-mediated reduction of the triple bond of a phosphaalkyne: X-ray structure of [Ru(PHFCH2But)Cl(CO)(CNC6H3Me2-2,6)(PPh3)2]BF4·CH2Cl2

Robin B. Bedford,   David E. Hibbs,   Anthony F. Hill,   Michael B. Hursthouse,   K. M. Abdul Malik  and  Cameron Jones  

Abstract

The reaction of [Ru(P[double bond, length half m-dash]CHBut)Cl(CO)(CNC6H3Me2-2,6)(PPh3)2] with HBF4 provides, rapidly and reversibly, the phosphaalkene complex [Ru(HP[double bond, length half m-dash]CHBut)Cl(CO)(CNC6H3Me2-2,6)(PPh3)2]+ which is converted by K[HF2] or [NBun4] F to the structurally characterised fluorophosphine complex [Ru(PHFCH2But)Cl(CO)(CNC6H3Me2-2,6)(PPh3)2]+.

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Article information

DOI
https://doi.org/10.1039/CC9960001895
Article type
Paper

Chem. Commun., 1996, 1895-1896

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Complete metal-mediated reduction of the triple bond of a phosphaalkyne: X-ray structure of [Ru(PHFCH2But)Cl(CO)(CNC6H3Me2-2,6)(PPh3)2]BF4·CH2Cl2

R. B. Bedford, D. E. Hibbs, A. F. Hill, M. B. Hursthouse, K. M. A. Malik and C. Jones, Chem. Commun., 1996, 1895 DOI: 10.1039/CC9960001895

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