Catalytic transfer hydrogenation of ethene and buta-1,3-deine with the aid of ammonia as a hydrogen donor is greatly enhanced by lanthanide (Ln)-promoted catalysts (Ln–Ni/SiO2, Ln–Ru/C, Ln–Cu/SiO2 and Ln–Ag/ZrO2), prepared by the reaction with Eu or Yb metal dissolved in liquid ammonia.
H. Imamura, K. Fujita, Y. Miura, K. Mizuno, Y. Sakata and S. Tsuchiya, Chem. Commun., 1996, 1841 DOI: 10.1039/CC9960001841
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