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Issue 14, 1996
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Ancillary ligand control of reactivity. Protonation at hydride vs. cyanide in trans-[FeH(CN)(R2PCH2CH2PR2)2](R = Et, Ph, p-tolyl) and X-ray crystal structure determination of trans-[FeH(CNH)(R2PCH2CH2PR2)2]BF4(R =p-tolyl)

Abstract

The ancillary ligands in trans-[FeH(CN)L2] control whether protonation occurs at hydride to produce a dihydrogen complex or at cyanide to produce a hydrogen isocyanide complex.

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Article type: Paper
DOI: 10.1039/CC9960001665
Chem. Commun., 1996, 1665-1666

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    Ancillary ligand control of reactivity. Protonation at hydride vs. cyanide in trans-[FeH(CN)(R2PCH2CH2PR2)2](R = Et, Ph, p-tolyl) and X-ray crystal structure determination of trans-[FeH(CNH)(R2PCH2CH2PR2)2]BF4(R =p-tolyl)

    P. I. Amrhein, S. D. Drouin, C. E. Forde, A. J. Lough and R. H. Morris, Chem. Commun., 1996, 1665
    DOI: 10.1039/CC9960001665

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