Treatment of the novel ring anion [C2But2P2Sb]– 4 with [Ru(ηC5R5)(MeCN)3]PF6, (R = H, Me), affords the compounds [Ru(η5-C5R5)(η5-C2But2P2Sb)](R = H 6, Me 7), which represent the first examples of complexes derived from a diphosphastioblyl ring; the X-ray crystal structure of 7 is described.
M. D. Francis, D. E. Hibbs, M. B. Hursthouse, C. Jones and K. M. A. Malik, Chem. Commun., 1996, 1591 DOI: 10.1039/CC9960001591
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