SCHEDULED MAINTENANCE
The magnitude of the shift in the ν(CO) IR spectrum of the MLCT excited state of [Re(CO)3Cl(bipy)](bipy = 2,2′-bipyridyl) in PrCN–EtCN solution, compared with the ground-state spectrum, decreases on cooling from fluid to glass; this ‘infrared rigidochromic’ effect is explained by the change in character of the MLCT state on glass formation.
I. P. Clark, M. W. George, F. P. A. Johnson and J. J. Turner, Chem. Commun., 1996, 1587 DOI: 10.1039/CC9960001587
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