Issue 13, 1996
From the journal:

Chemical Communications

Reaction of AlMe3 with [Mn{N(SiMe3)2}2(thf)] to form the unique methyl-bridged compound [{Mn(µ-Me)[N(SiMe3)2AlMe3]}2]

Mark Niemeyer  and  Philip P. Power  

Abstract

The synthesis and structural characterization of the novel transition-metal amido/alkyl compound [{Mn(µ-Me)[N(SiMe3)2AlMe3]}2] 1 via the reaction of AlMe3 with [Mn{N(SiMe3)2}2(thf)] are reported; 1 features a unique Mn(µ-Me)2Mn type of bridged structure stabilized by Mn–Me interactions involving a methyl group from AlMe3.

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Article information

DOI
https://doi.org/10.1039/CC9960001573
Article type
Paper

Chem. Commun., 1996, 1573-1574

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Reaction of AlMe3 with [Mn{N(SiMe3)2}2(thf)] to form the unique methyl-bridged compound [{Mn(µ-Me)[N(SiMe3)2AlMe3]}2]

M. Niemeyer and P. P. Power, Chem. Commun., 1996, 1573 DOI: 10.1039/CC9960001573

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