A palladium(II) complex with imino nitroxides, [PdCl2(immepy)2][immepy = 2-(6-methylpyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxy], shows a strong antiferromagnetic interaction between the coordinated imino nitroxides, which results from indirect overlap of radical SOMOs through a dxy orbital.
H. Oshio, A. Ohto and T. Ito, Chem. Commun., 1996, 1541 DOI: 10.1039/CC9960001541
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