Issue 12, 1996

Synthesis and characterisation of [Ru44-PC(CO)But}2(µ-CO)(CO)10] and [FeRu34-PC(CO)But}2(µ-CO)(CO)10]: cluster expansion by addition of metal carbonyl fragments to nido-clusters

Abstract

The two new µ4-phosphinidene cluster compounds [Ru44-PC(CO)But}2(µ-CO)(CO)10] and [FeRu34-PC(CO)But}2(µ-CO)(CO)10] are prepared by addition of the isolobal 12-valence electron fragments Ru(CO)2 and Fe(CO)2 to the nido-cluster [Ru33-PC(CO)But}2(CO)9].

Article information

Article type
Paper

Chem. Commun., 1996, 1455-1456

Synthesis and characterisation of [Ru44-PC(CO)But}2(µ-CO)(CO)10] and [FeRu34-PC(CO)But}2(µ-CO)(CO)10]: cluster expansion by addition of metal carbonyl fragments to nido-clusters

P. E. Gaede, B. F. G. Johnson, J. F. Nixon, M. Nowotny and S. Parsons, Chem. Commun., 1996, 1455 DOI: 10.1039/CC9960001455

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