Issue 12, 1996

Reversibility in free-radical reactions of aryltellurides with tributylstannyl radical

Abstract

119 Sn and 125Te NMR spectroscopies reveal that methyl, primary and secondary alkyl radicals, generated by reaction of phenyltelluroalkanes 4, 6, 7 with tributyltin hydride (benzene, AIBN initiator), are capable of displacing tributylstannyl radicals from (4-fluorophenyltelluro)tributylstannane to afford the 4-fluorophenyltelluroalkanes 3, 8, 9.

Article information

Article type
Paper

Chem. Commun., 1996, 1419-1420

Reversibility in free-radical reactions of aryltellurides with tributylstannyl radical

C. H. Schiesser and M. A. Skidmore, Chem. Commun., 1996, 1419 DOI: 10.1039/CC9960001419

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