The Zn derivative of a new stable open-box shaped pentamer of vertically linked porphyrins, formed quantitatively by treatment of tetrapyridylporphyrin with [Ru(TPP)CO], adds S-bonded RuII–Me2SO complexes which can enter the box to form adducts containing the rare bridging Me2SO.
E. Alessio, M. Macchi, S. Heath and L. G. Marzilli, Chem. Commun., 1996, 1411 DOI: 10.1039/CC9960001411
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