Issue 11, 1996
From the journal:

Chemical Communications

Site-selective hydrogenolysis, hydrogenation and alcoholysis involving the homometallic cluster [W6H5(CPri)(OPri)12]

Malcolm H. Chisholm  and  Keith S. Kramer  

Abstract

The octahedral W6 cluster [W6(µ-H)4H(µ-CPri(µ-OPri)5] 1 reacts with D2 to give D for H exchange, reacts reversibly with ethene, and in the presence of H2 yields ethane by exclusive use of the terminal W–H bond; 1 also reacts with (CD3)2CDOD to give selective alcoholysis of one terminal OR group.

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Article information

DOI
https://doi.org/10.1039/CC9960001331
Article type
Paper

Chem. Commun., 1996, 1331-1332

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Site-selective hydrogenolysis, hydrogenation and alcoholysis involving the homometallic cluster [W6H5(CPri)(OPri)12]

M. H. Chisholm and K. S. Kramer, Chem. Commun., 1996, 1331 DOI: 10.1039/CC9960001331

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