The octahedral W6 cluster [W6(µ-H)4H(µ-CPri(µ-OPri)5] 1 reacts with D2 to give D for H exchange, reacts reversibly with ethene, and in the presence of H2 yields ethane by exclusive use of the terminal W–H bond; 1 also reacts with (CD3)2CDOD to give selective alcoholysis of one terminal OR group.
M. H. Chisholm and K. S. Kramer, Chem. Commun., 1996, 1331 DOI: 10.1039/CC9960001331
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