The interaction of bare Pd2+ ions with framework oxygen in PdNaX calcined at 500°C results in an unusual 29Si MAS NMR band at δ– 79.5; line intensities indicate that bare Pd2+ ions are located preferentially close to highly basic sites exhibiting the Al richest environments; the strong Pd2+–framework interaction is reversibly released upon hydration/dehydration.
A. Sauvage, M. O. de Souza, M.-J. Peltre, P. Massiani and D. Barthomeuf, Chem. Commun., 1996, 1325 DOI: 10.1039/CC9960001325
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
