The synthesis of the inter- and intra-molecular donor-stabilized 1-metalla-2-sila-1,3-dienes Cl(H2C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH)SiMLn·OP(NMe2)3[MLn= Fe(CO)4 3a, Cr(CO)5 3b], Ph(PhHCCH)SiFe(CO)4·OP(NMe2)3 3c and (C6H4CH2NMe2-2)(H2CCH)Si MLn[MLn= Fe(CO)4 6a, Cr(CO)5 6b] is described; the X-ray structures of compounds 3c and 6b are reported.
H. Lang, M. Weinmann, W. Frosch, M. Büchner and B. Schiemenz, Chem. Commun., 1996, 1299 DOI: 10.1039/CC9960001299
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