The fullerenol C70Ph9OH is obtained as a minor product from the reaction of C70Cl10 with benzene/FeCl3and is chiral due to the attachment of a hydroxy group and a phenyl group across the 7,8-bond; this adjacency inhibits free rotation of the 8-phenyl group.
P. R. Birkett, A. G. Avent, A. D. Darwish, H. W. Kroto, R. Taylor and D. R. M. Walton, Chem. Commun., 1996, 1231 DOI: 10.1039/CC9960001231
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