Substituted 1,2,3,4,4a,9,9a,10-octahydroacridines with five stereogenic centres are formed highly diastereoselectively by the domino imine condensation–intramolecular polar [4π++ 2π]-cycloaddition of anilines and ω-unsaturated aldehydes.
U. Beifuss, A. Herde and S. Ledderhose, Chem. Commun., 1996, 1213 DOI: 10.1039/CC9960001213
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