The synthesis and crystal structure of Cs2Ga3As5O18 in which the Ga atoms are octahedrally and square-pyramidally coordinated are described: the three-dimensional structure is unique and contains the very rare triarsenate anion As3O105–.
K. Lin and K. Lii, Chem. Commun., 1996, 1137 DOI: 10.1039/CC9960001137
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