Ethlene preferentially attacks the oxygen closest to the titanium in HOO–Ti(OSiH3)3(MeOH) and HOO–TiL3(MeOH) cluster models of the active Ti-site in TS1 due to a substantially reduced electrostatic repulsion.
M. Neurock and L. E. Manzer, Chem. Commun., 1996, 1133 DOI: 10.1039/CC9960001133
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