The π-facial selectivity of 2-trifluoromethyl-1,3-dioxin-4-ones in conjugate addition and catalytic hydrogenation is described and an explanation of the selectivity by the Cieplak effect and anmeric effect is given.
M. Sato, F. Uehara, H. Kamaya, M. Murakami, C. Kaneko, T. Furuya and H. Kurihara, Chem. Commun., 1996, 1063 DOI: 10.1039/CC9960001063
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