Replacement of hydrogen by fluorine in a variety of organic compounds is accomplished with high efficiency in liquid hydrogen fluoride (aHF), at or below 20 °C, using the thermodynamically unstable fluorides RNiF3 and NiF4 the latter prepared in situ from K2NiF6 with BF3.
N. Bartlett, R. D. Chambers, A. J. Roche, R. C. H. Spink, L. Chacón and J. M. Whalen, Chem. Commun., 1996, 1049 DOI: 10.1039/CC9960001049
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