Treatment of tungsten-η1-7-oxabicyclo[2.2.1]heptadiene and -η1-7-oxabicyclo[2.2.1] heptene with CF3SO3H leads to atypical carbon–carbon bond scission and deoxygenation; the reaction intermediates in the bond scission involves a tungsten-η1-2-hydrofurylium cation.
L. Shiu, H. Shu, D. Cheng, S. Wang and R. Liu, Chem. Commun., 1996, 1041 DOI: 10.1039/CC9960001041
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