The generality of intermolecular N–H⋯H–Re hydrogen bonding is demonstrated in the crystal structure of the title complex, in which an imidazole of crystallization is involved in a three-centre hydrogen bond with an ReH2 group.
B. P. Patel, W. Yao, G. P. A. Yap, A. L. Rheingold and R. H. Crabtree, Chem. Commun., 1996, 991 DOI: 10.1039/CC9960000991
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