Manganese–oxo species grafted onto the internal walls of MCM-41 channels, showing a high redox catalytic activity for hydrocarbon oxidation, are prepared via the reaction of Mn2(CO)10 with Si–OH groups on the surface of mesoporous silica followed by subsequent heat treatment in air.
R. Burch, N. Cruise, D. Gleeson and S. C. Tsang, Chem. Commun., 1996, 951 DOI: 10.1039/CC9960000951
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