Issue 8, 1996
From the journal:

Chemical Communications

Synthesis and structure of a 2 CuII2 CuI constellation ligated by the new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol

Rajiv Bhalla,   Madeleine Helliwell  and  C. David Garner  

Abstract

The new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol, BimOH, is synthesized and employed to form the novel tetrameric constellation [Cu4(BimOH)2(BimO)2]4+, involving an (Nim)2CuII(OR)2CuII(Nim)2 centre with a CuII⋯ CuII separation of 2.998(4)Å and two CuI(Nim)2 moieties ca. 5 Å from the Cu2 centre, each with an N–Cu–N angle of 169.3(4)°.

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Article information

DOI
https://doi.org/10.1039/CC9960000921
Article type
Paper

Chem. Commun., 1996, 921-922

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Synthesis and structure of a 2 CuII2 CuI constellation ligated by the new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol

R. Bhalla, M. Helliwell and C. D. Garner, Chem. Commun., 1996, 921 DOI: 10.1039/CC9960000921

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