The palladium catalysed addition of pronucleophiles 1 to allenyl sulfides 2 gives the γ-addition products in good to high yields, whereas the addition to alkoxyallenes affords the α-addition products.
Y. Yamamoto, M. Al-Masum and A. Takeda, Chem. Commun., 1996, 831 DOI: 10.1039/CC9960000831
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