Issue 6, 1996

1,2-Distannylation and -disilylation of cyclic allenes

Abstract

Cyclo-1,2-dienes(C9–C13) are converted into the synthetically promissing 2,3-bis(trimethylsilyl)- and 2,3-bis(trimethylstannyl)cycloalk-1-enes by disilylation with lithium chlorotrimethylsilane in tetrahydrofuran, and Pd0-catalysed addition of hexaalkyldistannes, respectively.

Article information

Article type
Paper

Chem. Commun., 1996, 773-774

1,2-Distannylation and -disilylation of cyclic allenes

K. Kwetkat, B. H. Riches, J. Rosset, D. J. Brecknell, K. Byriel, C. H. L. Kennard, D. J. Young, U. Schneider, T. N. Mitchell and W. Kitching, Chem. Commun., 1996, 773 DOI: 10.1039/CC9960000773

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