A new route to peptide segments incorporating α,β-diamino acids either at the α- or β-positions is provided by enzymeimimetic ring opening of 3-amino β-lactams with α-amino acid esters promoted by sodium azide or potassium cyanide.
C. Palomo, J. M. Aizpurua, R. Galarza and A. Mielgo, Chem. Commun., 1996, 633 DOI: 10.1039/CC9960000633
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